Stable bromoallene oxides.
نویسندگان
چکیده
The first stable bromoallene oxides were obtained by the DMDO epoxidation of 1-bromo-1,3-di-tert-alkylallenes, producing the first crystalline allene oxide of any kind. The epoxidations are regioselective for the bromine-bearing Δ1,2 alkene, and also face selective producing single diastereomer E-olefin products.
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عنوان ژورنال:
- Chemical communications
دوره 52 75 شماره
صفحات -
تاریخ انتشار 2016